Product ID:SODIUM ORTHOVANADATE, S45450
MSDS Date:02/21/1991
FSC:6810
NIIN:00N027722
MSDS Number: BPYYR

FISHER SCIENTIFIC, CHEMICAL DIV.

1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100/800-424-9300(CHEMTREC)

Info Phone: 201-796-7100 OR 201-796-7523

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

VANADIC (II) ACID, TRISODIUM SALT; (SODIUM ORTHOVANADATE).

CAS: 13721-39-6

RTECS: YW1120000

Fraction By Weight: 100%

OSHA PEL SEE INGREDIENT NAME

ACGIH TLV: 0.05MG/M3 RDUST&FUME

AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEM

RTECS: 9999999ZZ

VICTIM IS CONSCIOUS,IMMED GIVE 2 TO 4 GLASSES OF

RTECS: 9999999ZZ

NO SPECIFIC ANTIDOTE. TREAT

RTECS: 9999999ZZ

AREA. LG SPILLS,DIKE FAR AHEAD OF SPILL FOR

RTECS: 9999999ZZ

PROFUSE LACRIMATION & BURNING SENSATION OF

RTECS: 9999999ZZ

(ACUTE)MAY CAUSE IRRIT OF MOUTH,

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: (ACUTE)DUSTS MAY CAUSE MEMB
IRRIT. VANADIUM CMPDS MAY CAUSE PALLOR, GREENISH-BLACK
DISCOLORATION OF TONGUE, PAROXSYMAL COUGH, DYSPNEA, CHEST PAIN,
BRONCH, RALES, RHONCHI, BRONCHOSPASM, TREMORS OF FINGERS & ARMS &
RADIOGRAPHIC RETICULATION. (CHRONIC)RPTD/PRLNGD EXPOS TO VANADIUM
CMPDS MAY CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: SEROUS/HEMORRHAGIC RHINITIS, SORE
THROAT, COUGH, TRACHEITIS, BRONCH, EXPECTORATION & CHEST PAIN MAY
RESULT. MORE SERIOUS EXPOS MAY CAUSE PULM EDEMA & PNEUM WHICH MAY
BE FATAL. INDIV WHO RECO VER MAY EXPERIENCE PERSISTENT BRONCH
RESEMBLING ASTHMA & BOUTS OF DYSPNEA. SKIN: (ACUTE)CONT W/DUSTS MAY
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE FROM EXPOS TO FRESH AIR IMMED. IF BRTHG STOPS,
PERFORM ARTF RESP. KEEP PERSON WARM & AT REST. TREAT SYMP &
SUPPORTIVELY. GET MD IMMED. SKIN:REMOVE CONTAM CLTHG & SHOES IMMED.
WASH AFFECTE D AREA W/SOAP/MILD DETERGENT & LRG AMTSOF WATER UNTIL
NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MIN). GET MD IMMED.
EYE:WASH IMMED W/LRG AMTS OF WATER/NORMAL SALINE, OCCASNLY LIFTING
UPPER (ING 2)

Flash Point:NON-FLAMMABLE
Extinguishing Media:DRY CHEMICAL, CO*2, WATER SPRAY OR REGULAR FOAM.
FOR LRG FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
.MOVE CNTNR FROM FIRE AREA IF CAN DO IT W/O RISK.EXTING USING AGENT
SUITABLE FOR SURROUND FIRE.AVOID(SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.

Spill Release Procedures:DO NOT TOUCH SPILLED MATL. STOP LEAK IF YOU
CAN W/O RISK. FOR SM SPILLS, TAKE UP W/SAND/OTHER ABSORB MATL &
PLACE IN CNTNRS FOR LATER DISP. FOR SM DRY SPILLS, W/CLEAN SHOVEL
PLACE MATL IN CLEAN, DRY C NTNR & COVER. MOVE CNTNRS FROM SPILL
(ING 5)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:THE SPECIFIC NIOSH/MSHA APPRVD RESP MUST BE
BASED ON CONTAM LEVS FOUND IN WORK PLACE, MUST BE BASED ON SPECIFIC
OPER & MUST NOT EXCEED THE WORKING LIMITS OF THE RESP. FOR FURTHER
INFORMATION REFER TO ORIGINAL MSDS .
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENT TO MEET
PUBLISHED EXPOSURE LIMITS.
Protective Gloves:PROTECTIVE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE (IMPERVIOUS) CLOTHING &
EQUIPMENT. EYEWASH FOUNTAIN WITHIN THE IMMEDIATE AREA.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:BREATHING VAPS & DUSTS. KEEP UPWIND. EFTS OF OVEREXP:
CAUSE REDNESS & IRRIT. VANADIUM CMPDS MAY CAUSE DERMAT, SKIN
LESIONS OF ECZEMATOUS TYPE & OCCASIONAL GENERALIZED URTICARIA.
(CHRON IC)MAY CAUSE DERMAT AFTER RPTD/PRLNGD EXPOS. EYE:
(ACUTE)DUSTS MAY CAUSE IRRIT. CONT W/VANADIUM CMPDS MAY CAUSE (ING
6)

HCC:N1
Melt/Freeze Pt:M.P/F.P Text:1562F,850C
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS, HEXAGONAL PRISMS.

Stability Indicator/Materials to Avoid:YES
NO DATA AVAILABLE.
Stability Condition to Avoid:MAY BURN BUT DOES NOT IGNITE READILY. PVNT
DISPERSION OF DUST IN AIR. DO NOT ALLOW SPILLED MATL TO CONTAM
WATER SOURCES.
Hazardous Decomposition Products:MAY RELEASE ACRID SMOKE AND HAZARDOUS
SODIUM OXIDE FUMES.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .

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particular situation.